The effect of various acids on the stability of cyclohexylidene-1,1-bisperoxide has particular significance for their potential application in industrial processes. However, there has been a lack of quantitative data on the thermal stability of geminal peroxides. In this study, the effect of different acids on the thermal decomposition of cyclohexylidene-1,1-bisperoxide at 130°C was investigated. The quantitative analysis of bishydroperoxide was performed using a spectrophotometric technique based on the formation of tri-iodide ions during iodide oxidation, which allows for the determination of peroxide concentrations up to 10⁻³ M. Kinetic parameters for the decomposition of cyclohexylidene-1,1-bishydroperoxide in benzonitrile with chloroacetic acid, trichloroacetic acid and pivalic acid were obtained during the experiment. It was observed that as acid strength increases, its impact on the rate of cyclohexylidene-1,1-bishydroperoxide decomposition naturally increases.
Author Biographies
Ristovski Daniel Vidoevich, Ufa Institute of Chemistry, Ufa federal Research Center of RAS
engineer at the Laboratory of Chemical Kinetics ORCID: 0000-0003-3092-9104ResearcherID: AAZ-6551-2020
Andriyashina Nadezhda Mikhailovna, fa Institute of Chemistry, Ufa federal Research Center of RAS
Cand. of Chemical Sciences, researcher at the Laboratory of Chemical KineticsORCID: 0000-0002-1985-4394 ResearcherID: J-6435-2018 Scopus ID: 6506234077
Grabovskii Stanislav Anatolyevich, Ufa Institute of Chemistry, Ufa federal Research Center of RAS
Cand. of Chemical Sciences, Assistant Professor, senior researcher at the Laboratory of Chemical Kinetics ORCID: 0000-0002-7754-5389 ResearcherID: JFJ-2384-2023 Scopus ID: 8257698500
