Synthesis of siloxy derivatives of ascorbic acid

Authors

  • Shatirova Mahruza Ismailovna Institute of Polymer Materials of Azerbaijan National Academy of Sciences, Republic of Azerbaijan

Keywords:

ascorbic acid, siloxy-derivatives, bromine- and dioxolane-containing derivatives, trialkyl(phenyl)ethoxysilanes

Abstract

The methods of the synthesis of siloxy-derivatives of ascorbic acid are developed, based on the interaction reactions of ascorbic acid and its bromine- and dioxolane-containing derivatives with trialkyl(phenyl) ethoxysilanes in the presence of silicon tetrachloride in a medium of ethyl alcohol. The yields of the purposeful products are quite high and are 75–85%. The structures of the synthesized compounds are confirmed by IR and NMR 1H and 13C spectroscopy. The synthesized compounds are optically active and have a positive (+) rotation sign

Author Biography

Shatirova Mahruza Ismailovna, Institute of Polymer Materials of Azerbaijan National Academy of Sciences, Republic of Azerbaijan

Head of Laboratory “Heterocyclic Monomers”, docent, PhD in Chemical Sciences

Published

2025-05-08

Issue

Section

Статьи