From dimpled to intergranular fracture: the role of aging in ductility degradation of Al–Cu–Li alloy

Authors

  • Diana Yunusovna Yuzbekova Belgorod National Research University
  • Ivan Sergeevich Zuiko Belgorod National Research University
  • Rustam Oskarovich Kaibyshev Belgorod National Research University

DOI:

https://doi.org/10.54708/26587572_2026_812412

Keywords:

Al-Cu-Li alloy, aged, mechanical properties, fractography, microstructure

Abstract

This study investigates the effect of aging on the mechanical properties and fracture behavior of the AA2055 (Al-Cu-Li) aluminum alloy. Specimens were subjected to artificial aging at 165 °C for 5, 50, and 150 h, corresponding to under-aged, peak-aged (maximum strength), and over-aged conditions, as defined by the aging curve. In the peak-aged condition, the alloy exhibits yield strength of 495 MPa, ultimate tensile strength of 530 MPa, and elongation to failure of ~ 6.2 %. Ductility drops sharply upon aging from the under-aged state (~24 %) to the peak-aged condition and remains low even after over-aging. Fractographic analysis reveals that the under-aged alloy fails by ductile transgranular fracture with dimple formation. Prolonged aging leads to matrix strengthening due to precipitation of the T1 (Al2CuLi) phase, concurrent with grain boundary degradation, which promotes strain localization and a transition to brittle intergranular fracture. The reduction in ductility from ~ 24 % to ~ 6 % with increasing aging time from 5 to 150 h is attributed to the evolution of the nanostructure of precipitates and a shift in the dominant fracture mechanism – from ductile (dimple) to intergranular.

References

Dursun T., Soutis C. Recent developments in advanced aircraft aluminium alloys. // Materials and Design, 56, 862–871(2014). DOI:10.1016/j.matdes.2013.12.002

Rioja R.J., Liu J. The evolution of Al-Li base products for aerospace and space applications. // Metallurgical and Materials Transactions A: Physical Metallurgy and Materials Science, 43, 3325–3337(2012). DOI:10.1007/s11661-012-1155-z

Smith K.P., Danie A. Aluminum-copper-lithium alloy 2050 developed for medium to thick plate. // Journal of Materials Engineering and Performance, 19, 841–847(2024). DOI:10.1007/s11665-009-9554-z

Sun J., Wu G., Zhang L., Liu W., Zhang J., Shi C., Li W. Role of Cu on the mechanical properties and microstructures evolution of Al-xCu-1Li-0.4Mg-1Zn-0.1Zr alloys. // Materials Science and Engineering: A, 792, 139833(2020). DOI:10.1016/j.msea.2020.139833

Gumbmann E., Lefebvre W., De Geuser F., Sigli C., Deschamps A. The effect of minor solute additions on the precipitation path of an Al-Cu-Li alloy. // Acta Materialia, 115, 104–114(2016). DOI:10.1016/j.actamat.2016.05.050

Li H., Tang Y., Zeng Z., Zheng Z., Zheng F. Effect of ageing time on strength and microstructures of an Al – Cu – Li – Zn – Mg – Mn – Zr alloy. // Materials Science and Engineering: A, 498, 314–320(2008). DOI:10.1016/j.msea.2008.08.001

Liu Q., Zhu R., Liu D., Xu Y., Li J., Chen Y., Zhang X., Zheng Z. Correlation between arti fi cial aging and intergranular corrosion sensitivity of a new Al-Cu-Li alloy sheet. // Materials and Corrosion, 68, 65–76(2016). DOI:10.1002/maco.201609090

Dorin T., De Geuser F., Lefebvre W., Sigli C., Deschamps A. Strengthening mechanisms of T1 precipitates and their influence on the plasticity of an Al-Cu-Li alloy. // Materials Science and Engineering: A, 605, 119–126(2014). DOI:10.1016/j.msea.2014.03.024

Donnadieu P., Shao Y., De Geuser F., Botton G.A., Lazar S., Cheynet M. Atomic structure of T1 precipitates in Al – Li – Cu alloys revisited with HAADF-STEM imaging and small-angle X-ray scattering. // Acta Materialia, 59, 462–472(2011). DOI:10.1016/j.actamat.2010.09.044

Jata K.V., Vasudevan A.K. Effect of fabrication and microstructure on the fracture initiation and growth toughness of Al – Li – Cu alloys. // Materials Science and Engineering: A, 241, 104–113(1998). DOI: 10.1016/S0921-5093(97)00479-6

Decreus B., Deschamps A., Donnadieu P., Ehrström J.C. On the role of microstructure in governing fracture behavior of an aluminum-copper-lithium alloy. // Materials Science and Engineering: A, 586, 418–427(2013). DOI:10.1016/j.msea.2013.06.075

Zhang S., Zeng W., Yang W., Shi C. Ageing response of a Al-Cu-Li 2198 alloy. // Materials and Design, 63, 368–374(2014). DOI:10.1016/j.matdes.2014.04.063

Li H., Huang D., Kang W., Liu J., Ou Y., Li D. Effect of different aging processes on the microstructure and mechanical properties of a novel Al–Cu–Li alloy. // Journal of Materials Science and Technology, 32, 1049–1053(2016). DOI:10.1016/j.jmst.2016.01.018

Li A., Mg C. A study aimed at determining and understanding the fracture behaviour of an Al – Li – Cu – Mg – Zr alloy 8090. // International journal of fracture, 161, 141-159(2014). DOI:10.1007/s10704-009-9439-z

Pasang T., Symonds N., Moutsos S., Wanhill R.J.H., Lynch S.P. Low-energy intergranular fracture in Al-Li alloys. // Engineering Failure Analysis, 22, 166–178(2012). DOI:10.1016/j.engfailanal.2012.01.006

Lynch S.P. Effects of ageing treatments on resistance to intergranular fracture of 8090 Al-Li alloy plate. // Materials Science and Engineering: A, 172, 79–93(1993). DOI: 10.1016/0921-5093(93)90428-H

Lynch S.P., Muddle B.C., Pasang T. Ductile-tobrittle fracture transitions in 8090 Al–Li alloys. // 49, 2863–2874, (2001). DOI: 10.1016/S1359-6454(01)00217-8

Cassada W.A., Shiflet G.J., Starke Jr E.A. The effect of germanium on the precipitation and deformation behavior of Al 2Li alloys. // Acta metallurgica, 34, 367–378(1986). DOI: 10.1016/0001-6160(86)90072-6

Vasudevan A.K., Doherty R.D. Grain boundary ductile fracture in precipitation hardened aluminum alloys. // Acta metallurgica, 35, 1193–1219 (2022). DOI:10.1016/0001-6160(87)90001-0

Goswami R., Bernstein N. Effect of interfaces of grain boundary Al2CuLi plates on fracture behavior of Al-3Cu-2Li. // Acta Materialia, 87, 399–410(2015). DOI:10.1016/j.actamat.2014.12.025

Kim J., Jeun J., Chun H., Rim Y., Yoo J., Yoon J., Lee H. Effect of precipitates on mechanical properties of AA2195. // Journal of Alloys and Compounds, 669, 187–198(2016). DOI:10.1016/j.jallcom.2016.01.229

Jiang B., Cao F., Wang H., Jiang Y., Shen F., Wang B. Effect of aging time on the microstructure evolution and mechanical property in an Al-Cu-Li alloy sheet. // Materials Science and Engineering: A, 740, 157-164(2018). DOI:10.1016/j.msea.2018.10.064

Lynch S.P., Wanhill R.J.H., Byrnes R.T., Bray G.H. Chapter 13-Fracture toughness and fracture modes of aerospace aluminum à lithium alloys. Butterworth-Heinemann, 2014. P. 415–455. DOI:10.1016/B978-0-12-401698-9.00013-6

Yuzbekova D., Zuiko I.S. Effect of solution treatment temperature on the microstructure and properties of 2055 aluminium alloy // Materials. Technologies. Design. 6, 3(18) 91–101(2024). (In Russian) [Юзбекова Д.Ю., Зуйко И.С., Бодякова А.И., Кайбышев Р.О. Влияние температуры обработки на твердый раствор на микроструктуру и свойства алюминиевого сплава 2055 // Материалы. Технологии. Дизайн. 6, 3(18), 91–101(2024)]. DOI:10.54708/26587572

Ber, L.B. On the stages of aging of aluminum alloys. // Technology of light alloys. 4, 66–76(2013). (In Russian) [Бер Л.Б. О стадиях старения алюминиевых сплавов // Технология легких сплавов. 4, 66–76(2013).

Zhang P., Liu G., Sun J. A critical review on the Portevin-Le Chatelier effect in aluminum alloys. // Journal of Central South University, 29, 744–766(2022). DOI:10.1007/s11771-022-4977-x

Aboulfadl H., Deges J., Choi P., Raabe D. Dynamic strain aging studied at the atomic scale. // Acta Materialia, 86, 34–42(2015). DOI:10.1016/j.actamat.2014.12.028

Published

2025-11-12

How to Cite

Yuzbekova Д. Ю., Zuiko И. С. ., & Kaibyshev Р. О. (2025). From dimpled to intergranular fracture: the role of aging in ductility degradation of Al–Cu–Li alloy. Materials. Technologies. Design., 8(1 (24), 12–21. https://doi.org/10.54708/26587572_2026_812412